|
|
(2E)-4-guanidino-2-methyl-but-2-enoyl-[CyrB_PKS] + malonyl-CoA + NADPH + H+ <=> (4E,6E,9S,10E)-12-guanidino-9-hydroxy-10-methyl-3-oxododeca-4,6,10-trienoyl-[CyrF_PKS] + CO2 + CoA + H2O + NADP+
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-20453
|
|
|
|
L-arginine + glycine <=> L-ornithine + Guanidinoacetate
|
2.1.4.1
glycine amidinotransferase
|
–
|
| |
BRENDA:
BR43955
KEGG:
R00565
MetaCyc:
GLYCINE-AMIDINOTRANSFERASE-RXN
SABIO-RK:
975
|
|
|
|
7-deoxycylindrospermopsin + O2 + 2-oxoglutarate <=> cylindrospermopsin + succinate + CO2
|
1.14.11.70
7-deoxycylindrospermopsin hydroxylase
|
–
|
| |
BRENDA:
BR52981
KEGG:
R12509
MetaCyc:
RXN-20448
|
|
|
|
L-arginine + (4E,6E,9S,10E)-12-guanidino-9-hydroxy-10-methyl-3-oxododeca-4,6,10-trienoyl-[CyrF_PKS] <=> L-ornithine + desulfo-7-deoxycylindrospermopsin + polyketide-[acp]
|
2.1.4
|
–
|
| |
MetaCyc:
RXN-20450
|
|
|
|
7-deoxycylindrospermopsin + O2 + 2-oxoglutarate <=> 7-epi-cylindrospermopsin + succinate + CO2
|
1.14.11.70
7-deoxycylindrospermopsin hydroxylase
|
–
|
| |
BRENDA:
BR52982
KEGG:
R12510
MetaCyc:
RXN-20454
|
|
|
|
Guanidinoacetate + polyketide-[acp] + ATP <=> guanidinoacetyl-[polyketide_synthase] + AMP + diphosphate
|
6.2.1
|
–
|
| |
MetaCyc:
RXN-20452
|
|
|
|
S-adenosyl-L-methionine + guanidinoacetyl-[polyketide_synthase] + malonyl-CoA + NADPH + H+ <=> (2E)-4-guanidino-2-methyl-but-2-enoyl-[CyrB_PKS] + CO2 + S-adenosyl-L-homocysteine + CoA + H2O + NADP+
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-20451
|
|
|
|
3''-phosphoadenylyl-sulfate + desulfo-7-deoxycylindrospermopsin <=> adenosine_3,5''-bisphosphate + 7-deoxycylindrospermopsin + H+
|
2.8.2
|
–
|
| |
MetaCyc:
RXN-20449
|
|
